Chakraborty, Kajal and Devakumar, C and Tomar, Shiv M S and Kumar, Rajendra (2003) Synthesis and Quantitative Structure-Activity Relationships of Oxanilates as Chemical Hybridizing Agents for Wheat (Triticum aestivum L.)‡. Journal of Agricultural and Food Chemistry, 51. pp. 992-998.
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Abstract
Chemical hybridizing agents (CHAs) can facilitate two-line breeding in heterosis programs of crops. Twenty-seven oxanilates having different aromatic substitutions were synthesized and screened as CHAs on two genotypes of wheat, PBW 343 and HD 2733, during two Rabi(winter) seasons, 2000- 01 and 2001-02. The oxanilates prepared by thermal condensation of anilines with diethyl oxalate or by acylation with ethoxycarbonyl methanoyl chloride were sprayed at 1000 and 1500 ppm at the premeiotic stage of wheat, when the length of the emerging spike of the first node was 7-8 mm. Pollen sterility and spikelet sterility were measured in each treatment. Ethyl oxanilates 5, 6, and 25, containing 4-F, 4-Br, and 4-CF3 aromatic substituents, respectively, induced greater than 98% spikelet sterility, the desired level, at 1500 ppm. Quantitative structure-activity relationship analysis revealed a direct relationship between Fp and molecular mass but an inverse relationship between MR, ES, and R in influencing the bioactivity. Several F1 hybrids were developed using 5, and at least one showed heterosis.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | Chemical hybridizing agents (CHAs); Triticum aestivumL. wheat; male sterility; oxanilates; ethyl N-aryl carbamoyl methanoate; QSAR |
| Subjects: | Fish Biotechnology > Bioactive compound |
| Divisions: | CMFRI-Kochi > Marine Biotechnology, Fish Nutrition and Health Division Subject Area > CMFRI > CMFRI-Kochi > Marine Biotechnology, Fish Nutrition and Health Division CMFRI-Kochi > Marine Biotechnology, Fish Nutrition and Health Division Subject Area > CMFRI-Kochi > Marine Biotechnology, Fish Nutrition and Health Division |
| Depositing User: | Arun Surendran |
| Date Deposited: | 26 Feb 2014 10:12 |
| Last Modified: | 09 Sep 2015 15:58 |
| URI: | http://eprints.cmfri.org.in/id/eprint/9959 |
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